This must be a question that must have been asked a thousand
times. but i do not have any answer to it.

How do I transfer data from my Webpage to an Excell Spreadsheet using
VB.Net? My data is not in the form of any datagrid or datalists,
Its just simple labels and textboxes. Ideally I would like to transfer the data one cell at a time,

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You can access Excel through it's API's by adding a COM reference to the Microsoft Excel 9.0 Library, or through ADO.NET using the System.Data.OLEDB objects.

check out http://www.greggriffiths.org/webdev/both/excel which covers this for Classic ASP, but many of the links and content will be useful.