Hi williams
You can do this steps:
1-start visual studio
2-select File->New web site
3-select ASP.Net Empty Web site
4-Click OK
5-select website->add new items
6-click OK
Now You have New web page in asp.net.
But It's only beginning.
Really I Read The Imar Spaanjaar book And find It Best book For beginning ASP.Net. You can Find it in wrox :
Beginning ASP.NET 4 in C# and
VB.
Imar also answer your questions in this forum.