First the easy way to read this book is patience..right!
second in chapter one there is no important things to read it but you can read it if you would.
In chapter two , to read this chapter first you should read chapter 6 themes and skins in Professional ASP.NET 4 in C# and VB book trust me this is the best way.
In chapter three you should read in focus chapter 14 LINQ and the ADO.NET Entity Framework in Beginning Asp.net 4 in C# and VB book the best book for everyone want to learn asp.net. If you have time you can read chapter 9 Querying with linQ in Professional ASP.NET 4 in C# and VB book.
This all thing you need to get start to read Asp.net 3.5 website Programming Problem Design Solution book.
I will shared new post to how reading chapter 4,5,6 after finish from it.