<system.net>
  <mailSettings>
    <smtp from="[email protected]" deliveryMethod="Network">
      <network host="smtp.live.com" port="25" userName="[email protected]" 
                 password="mypassword" />
    </smtp>
  </mailSettings>
</system.net>

 
MailMessage myMessage = new MailMessage();
myMessage.Subject = "Test Message";
myMessage.Body = "Hellow world, from planet Wrox";
myMessage.From = new MailAddress("[email protected]");
myMessage.To.Add(new MailAddress("[email protected]"));
SmtpClient mySmtpClient = new SmtpClient();
mySmtpClient.EnableSsl = true;
mySmtpClient.Send(myMessage);

Server Error in '/' Application.
--------------------------------------------------------------------------------

The SMTP server requires a secure connection or the client was not authenticated. The server response was: 5.7.0 Must issue a STARTTLS command first 
Description: An unhandled exception occurred during the execution of the current web request. Please review the stack trace for more information about the error and where it originated in the code. 

Exception Details: System.Net.Mail.SmtpException: The SMTP server requires a secure connection or the client was not authenticated. The server response was: 5.7.0 Must issue a STARTTLS command first

Source Error: 

The source code that generated this unhandled exception can only be shown when compiled in debug mode. To enable this, please follow one of the below steps, then request the URL:

1. Add a "Debug=true" directive at the top of the file that generated the error. Example:

  <%@ Page Language="C#" Debug="true" %>

or:

2) Add the following section to the configuration file of your application:

<configuration>
   <system.web>
       <compilation debug="true"/>
   </system.web>
</configuration>

Note that this second technique will cause all files within a given application to be compiled in debug mode. The first technique will cause only that particular file to be compiled in debug mode.

Important: Running applications in debug mode does incur a memory/performance overhead. You should make sure that an application has debugging disabled before deploying into production scenario.  

Stack Trace: 


[SmtpException: The SMTP server requires a secure connection or the client was not authenticated. The server response was: 5.7.0 Must issue a STARTTLS command first]
   System.Net.Mail.MailCommand.CheckResponse(SmtpStatusCode statusCode, String response) +1061671
   System.Net.Mail.MailCommand.Send(SmtpConnection conn, Byte[] command, String from) +41
   System.Net.Mail.SmtpTransport.SendMail(MailAddress sender, MailAddressCollection recipients, String deliveryNotify, SmtpFailedRecipientException& exception) +101
   System.Net.Mail.SmtpClient.Send(MailMessage message) +1480
   Practice_Email.Page_Load(Object sender, EventArgs e) +169
   System.Web.Util.CalliHelper.EventArgFunctionCaller(IntPtr fp, Object o, Object t, EventArgs e) +14
   System.Web.Util.CalliEventHandlerDelegateProxy.Callback(Object sender, EventArgs e) +35
   System.Web.UI.Control.OnLoad(EventArgs e) +99
   System.Web.UI.Control.LoadRecursive() +50
   System.Web.UI.Page.ProcessRequestMain(Boolean includeStagesBeforeAsyncPoint, Boolean includeStagesAfterAsyncPoint) +627

using System;
using System.Collections;
using System.Configuration;
using System.Data;
using System.Linq;
using System.Web;
using System.Web.Security;
using System.Web.UI;
using System.Web.UI.HtmlControls;
using System.Web.UI.WebControls;
using System.Web.UI.WebControls.WebParts;
using System.Xml.Linq;
using System.Net.Mail;

public partial class Practice_Email : BasePage
{
    protected void Page_Load(object sender, EventArgs e)
    {
        MailMessage myMessage = new MailMessage();
        myMessage.Subject = "Practice Message";
        myMessage.Body = "Hello guys, this is an email from Salford Student Bookshop";

        myMessage.From = new MailAddress("[email protected]", "Lee Bell");
        myMessage.To.Add(new MailAddress("[email protected]", "Lee Bell"));

        SmtpClient mySmtpClient = new SmtpClient();
        mySmtpClient.Send(myMessage);
    }
}

  <system.net>
    <mailSettings>
      <smtp from="[email protected]" deliveryMethod="Network">
        <network host="smtp.live.com" port="25"
        userName="[email protected]" password="*******"  />
      </smtp>
    </mailSettings>
  </system.net>
</configuration>

protected void buttonSend_Click(object sender, EventArgs e)
    {
        if (Page.IsValid)
        {
            string fileName = Server.MapPath("~/App_Data/ContactUs.txt");
            string mailBody = System.IO.File.ReadAllText(fileName);

            mailBody = mailBody.Replace("##Name##", textName.Text);
            mailBody = mailBody.Replace("##Email##", textEmailAddress.Text);
            mailBody = mailBody.Replace("##HomePhone##", homePhone.Text);
            mailBody = mailBody.Replace("##MobilePhone##", mobilePhone.Text);
            mailBody = mailBody.Replace("##Comments##", textComments.Text);

            MailMessage myMessage = new MailMessage();
            myMessage.Subject = "Query from Salford Student Books User";
            myMessage.Body = mailBody;

            myMessage.From = new MailAddress("[email protected]", "Farid Menziane");
            myMessage.To.Add(new MailAddress("[email protected]", "Lee Bell"));

            SmtpClient mySmtpClient = new SmtpClient();
            mySmtpClient.Send(myMessage);

            LabelMessage.Visible = true;
            FormTable.Visible = false;
        }

    }

Dear Staff member,

The following user has sent a query to us. Please see below:

Name:                    ##Name##
E-mail address:          ##Email##
Home telephone:          ##HomePhone##
Mobile phone:            ##MobilePhone##
Comments:                ##Comments##