Hi there,
Most of it will work, but some of it won't. The 4.5 book uses some tools and technologies that have changed or have been deprecated in Visual Studio 2013 / .NET 4.5.1. You're probably best off using the version of VS that the book is targeting, so you can either get a copy of the 4.5.1. book or download VS Express 2012 here:
http://www.microsoft.com/en-us/downl....aspx?id=34673
Cheers,
Imar