//Data selects nothing because there is no element in your source document called Data. There is an element called {http://something.com/Documents/Schemas/doc.xsd}Data (using James Clark's {uri}local notation for namespaced names), and to select this element you need to use the path expression
//x:Data
where some containing element (e.g. xsl:stylesheet) defines
xmlns:x="http://something.com/Documents/Schemas/doc.xsd"
Michael Kay
http://www.saxonica.com/
Author, XSLT Programmer's Reference and XPath 2.0 Programmer's Reference