First of all, if you are brand new to programming, it's not obvious that
VB or C# are good starting points. You have to learn quite a bit to start getting useful work done.
You can learn some of the basics in tools like Microsoft Access, for example.
But if you really want to learn
VB, then you need to get one of the beginner books and work through it in detail. Wrox has one, of course, though the 2005 version is probably no longer in print. However, the 2008 version is going to be very similar. Check out Amazon and find one you like.