Here is a little example from BOL from the EncryptByKey (Transact-SQL) topic
USE AdventureWorks;
GO
-- Create a column in which to store the encrypted data.
ALTER TABLE HumanResources.Employee
ADD EncryptedNationalIDNumber varbinary(128);
GO
-- Open the symmetric key with which to encrypt the data.
OPEN SYMMETRIC KEY SSN_Key_01
DECRYPTION BY CERTIFICATE HumanResources037;
-- Encrypt the value in column NationalIDNumber with symmetric key
-- SSN_Key_01. Save the result in column EncryptedNationalIDNumber.
UPDATE HumanResources.Employee
SET EncryptedNationalIDNumber
= EncryptByKey(Key_GUID('SSN_Key_01'), NationalIDNumber);
GO
David Lundell
Principal Consultant and Trainer
www.mutuallybeneficial.com