You can find documentation in the msdn. Select the ListItems property of the ListView control and that gives you this example:
Private Sub Form_Load()
' Add ColumnHeaders. The width of the columns is
' the width of the control divided by the number of
' ColumnHeader objects.
ListView1.ColumnHeaders. _
Add , , "Author", ListView1.Width / 3
ListView1.ColumnHeaders. _
Add , , "Author ID", ListView1.Width / 3, _
lvwColumnCenter
ListView1.ColumnHeaders. _
Add , , "Birthdate", ListView1.Width / 3
' Set View property to Report.
ListView1.View = lvwReport
' Declare object variables for the
' Data Access objects.
Dim myDb As Database, myRs As Recordset
' Set the Database to the BIBLIO.MDB database.
' IMPORTANT: the Biblio.mdb must be on your
' machine, and you must set the correct path to
' the file in the OpenDatabase function below.
Set myDb = DBEngine.Workspaces(0) _
.OpenDatabase("c:\Program Files\
VB\BIBLIO.MDB")
' Set the recordset to the "Authors" table.
Set myRs = _
myDb.OpenRecordset("Authors", dbOpenDynaset)
' Declare a variable to add ListItem objects.
Dim itmX As ListItem
' While the record is not the last record,
' add a ListItem object. Use the author field for
' the ListItem object's text. Use the AuthorID
' field for the ListItem object's SubItem(1).
' Use the "Year of Birth" field for the ListItem
' object's SubItem(2).
While Not myRs.EOF
Set itmX = ListView1.ListItems. _
Add(, , CStr(myRs!Author)) ' Author.
' If the AuthorID field is not null, then set
' SubItem 1 to it.
If Not IsNull(myRs!Au_id) Then
itmX.SubItems(1) = CStr(myRs!Au_id)
End If
' If the birth field is not Null, set
' SubItem 2 to it.
If Not IsNull(myRs![Year Born]) Then
itmX.SubItems(2) = myRs![Year Born]
End If
myRs.MoveNext ' Move to next record.
Wend